Layered compounds based on molybdenum disulfide and ruthenium arene complexes
نویسندگان
چکیده
منابع مشابه
New arene ruthenium complexes with planar chirality
1,2,4-Trimethyl-cyclohexadiene reacts with RuCl3 nH2O in refluxing ethanol to afford quantitatively [RuCl2(1,2,4-C6H3Me3)] (1), the coordination of 1,2,4-trimethylbenzene to the ruthenium atom introducing planar chirality at the g-arene ligand. Th dinuclear complex 1 reacts with two equivalents of triphenylphosphine (PPh3) to give quantitatively, as a racemic mixture o enantiomers, [RuCl2(1,2,4...
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The antimetastatic ruthenium(II) compounds [Ru(η(6)-p-cymene)Cl(2)(PTA)] (PTA = 1,3,5-triaza-7-phosphaadamantane) (RAPTA-C) and [Ru(η(6)-toluene)Cl(2)(PTA)] (RAPTA-T), as well as their analogues [Ru(η(6)-p-cymene)Cl(2)(DAPTA)] (DAPTA = (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)) (DAPTA-C) and [Ru(η(6)-toluene)Cl(2)(DAPTA)] (DAPTA-T), respectively, were tested in in vitro bioassay...
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A series of Ru(II) arene complexes of mono- and bidentate N-donor ligands with carboxyl or ester groups and chlorido ancillary ligands were synthesised and structurally characterised. The complexes have a distorted tetrahedral piano-stool geometry. The binding interaction was studied with calf thymus DNA (CT-DNA) by absorption titration, viscosity measurement, thermal melting, circular dichrois...
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This paper presents a systematic study of intrinsic characteristics of layered two-dimensional transitionmetal dichalcogenides, with a focus on molybdenum disulfide, molybdenum diselenide, and tungsten diselenide. Recent advances in high-resolution transmission electron microscopy (HRTEM) have made atomic-resolution imaging possible, thus enabling one to closely examine real and reciprocal spac...
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ژورنال
عنوان ژورنال: Journal of Materials Chemistry
سال: 1997
ISSN: 0959-9428,1364-5501
DOI: 10.1039/a604733e